THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORORUTHENIUM(II)

被引：21

作者：

LOBANA, TS ^{[1
]}

SINGH, R ^{[1
]}

TIEKINK, ERT ^{[1
]}

机构：

[1] UNIV ADELAIDE, DEPT PHYS & INORGAN CHEM,JORDAN LABS, ADELAIDE, SA 5001, AUSTRALIA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1990年 / 21卷 / 03期

基金：

澳大利亚研究理事会;

关键词：

diphosphine; Ruthenium(II); X-ray structure;

D O I：

10.1080/00958979009409719

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, trans-[Ru(dppe)2Cl2], has Ī symmetry such that the chloride atoms are exactly trans. The coordination geometry is distorted octahedral owing, in part, to the restricted bite distance of the chelating dppe ligands. Important interatomic parameters are Ru–Cl 2.436(1), Ru–P(1), 2.389(1) Ru–P(2) 2.369(1) Å and P(1)–Ru–P(2) 82.1(1)°. The compound crystallizes as a dichloromethane solvate in the monoclinic space group C2/c with unit cell dimensions a = 27.995(3), b = 13.85(1), c = 13.265(3) Å, Å = 105.38(2)° and Z = 4. The structure was refined by a full-matrix least-squares procedure to final R = 0.038 for 3522 reflections with I ≥ 2.5σ(I). © 1990 Gordon and Breach Science Publishers S.A.

引用

页码：225 / 229

页数：5

共 11 条

[1] NEW PREPARATIONS AND MOLECULAR-STRUCTURES OF CIS-MCL2(PH2PCH2PPH2)2, CIS-RUCL2(PH2PCH2PPH2)2, CIS-OSCL2(PH2PCH2PPH2)2 AND TRANS-RUCL2(PH2PCH2PPH2)2 [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

SCHWOTZER, W .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 84 (02) :179-185

[2] MECHANISM OF FORMATION AND CRYSTAL-STRUCTURE OF TRANS-DICHLOROTETRAKIS-(DIMETHYLPHOSPHINE)RUTHENIUM(II), RUCL2[PH(CH3)2]4 [J].

COTTON, FA ;

FRENZ, BA ;

HUNTER, DL .

INORGANICA CHIMICA ACTA, 1976, 16 (JAN) :203-207

[3]

HAMILTON WC, 1974, INT TABLES XRAY CRYS, V4, P99

[4]

JOHNSON CK, 1971, ORNL3794 REP

[5] ORTHORHOMBIC MODIFICATION OF DICHLOROBIS(TRIPHENYLPHOSPHINE)MERCURY(II) [J].

LOBANA, TS ;

SANDHU, MK ;

SNOW, MR ;

TIEKINK, ERT .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1988, 44 :179-181

[6] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A WEAK MOLECULAR ADDUCT OF DIPHENYLMERCURY(II) WITH 1,2-BIS(DIPHENYLPHOSPHINOTHIOYL)ETHANE [J].

LOBANA, TS ;

SANDHU, MK ;

TIEKINK, ERT .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (05) :1401-1403

[7] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF CHLORO[2(1H)-PYRIDINETHIONE-S]-BIS(TRIPHENYLPHOSPHINE)COPPER(I) [J].

LOBANA, TS ;

BHATIA, PK ;

TIEKINK, ERT .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (04) :749-751

[8] POLYPHOSPHINE COMPLEXES OF RUTHENIUM(II) [J].

MASON, R ;

MEEK, DW ;

SCOLLARY, GR .

INORGANICA CHIMICA ACTA, 1976, 16 (JAN) :L11-L12

[9]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

[10] HYDROGENATION REACTIONS WITH RUCL2(L-L)2 (L-L= BIDENTATE PHOSPHINE) [J].

SUAREZ, T ;

FONTAL, B ;

GARCIA, D .

JOURNAL OF MOLECULAR CATALYSIS, 1986, 34 (02) :163-171

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