UNUSUAL INITIAL PRODUCT DISTRIBUTIONS FOR CYCLOPENTANE/D2 EXCHANGE-REACTIONS ON PT CATALYSTS - REMARKABLE EFFECT OF MGO AS SUPPORT

被引：15

作者：

BAIRD, T ^{[1
]}

KELLY, EJ ^{[1
]}

PATTERSON, WR ^{[1
]}

ROONEY, JJ ^{[1
]}

机构：

[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 19期

关键词：

D O I：

10.1039/c39920001431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Initial deuterio-isomer distribution patterns in cyclopentane/D2 exchange reactions at 343 K reflect Pd-like character on Pt/MgO in sharp contrast to Pt/SiO2 or Pt/Al2O3, indicating a support effect, which may explain the enhanced behaviour of Pt/MgO catalysts for aromatisation reactions.

引用

页码：1431 / 1433

页数：3

共 16 条

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