SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (NEOPENTYL)(OCTAETHYLPORPHYRINATO)RUTHENIUM COMPLEXES, INCLUDING [RU(OEP)NP]2(MU-LI)2

被引：25

作者：

ALEXANDER, CS ^{[1
]}

RETTIG, SJ ^{[1
]}

JAMES, BR ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of neopentyllithium (LiNp) with the octaethylporphyrin complex Ru(OEP)Cl2 yields Ru-(OEP)Np (1), which can be treated with further LiNp to give [Ru(OEP)Np]2(mu-Li)2 (2). The structures of 1 (the first for an iron-group metalloporphyrin alkyl) and the more remarkable 2, revealing two Li atoms sandwiched between metalloporphyrin moieties, are determined.

引用

页码：2542 / 2544

页数：3

共 26 条

[1] ARIEL S, 1983, CAN J CHEM, V62, P755
[2] SYNTHESIS AND CHARACTERIZATION OF LITHIUM, SODIUM, AND POTASSIUM PORPHYRIN COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF LI2(C6H12O2)2TMPP, NA2(THF)4OEP, AND K2(PYRIDINE)4OEP
ARNOLD, J
DAWSON, DY
HOFFMAN, CG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (07) : 2707 - 2713
[3] THE ORGANOMETALLIC CHEMISTRY OF TRANSITION-METAL PORPHYRIN COMPLEXES
BROTHERS, PJ
COLLMAN, JP
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1986, 19 (07) : 209 - 215
[4] SYNTHESIS OF RUTHENIUM(III) AND OSMIUM(III) PORPHYRIN MONO-ALKYL AND MONO-ARYL COMPLEXES AND OF A NOVEL 6-COORDINATE ASYMMETRICALLY SUBSTITUTED RUTHENIUM(IV) PORPHYRIN COMPLEX, [RU(OEP)(PH)(ME)]
COLLMAN, JP
ROSE, E
VENBURG, GD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (01) : 11 - 12
[5] OXIDATION OF RUTHENIUM(II) AND RUTHENIUM(III) PORPHYRINS - CRYSTAL-STRUCTURES OF MU-OXO-BIS[(PARA-METHYLPHENOXO)(MESO-TETRAPHENYLPORPHYRINATO)-RUTHENIUM(IV)] AND ETHOXO(MESO-TETRAPHENYLPORPHYRINATO)-(ETHANOL)RUTHENIUM(III)-BISETHANOL
COLLMAN, JP
BARNES, CE
BROTHERS, PJ
COLLINS, TJ
OZAWA, T
GALLUCCI, JC
IBERS, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (18) : 5151 - 5163
[6] SYNTHESIS, PROTON NMR-SPECTROSCOPY, AND STRUCTURAL CHARACTERIZATION OF BINUCLEAR RUTHENIUM PORPHYRIN DIMERS
COLLMAN, JP
BARNES, CE
SWEPSTON, PN
IBERS, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (12) : 3500 - 3510
[7] REACTIVITY OF ZERO-VALENT METALLOPORPHYRIN DIANIONS TOWARD ORGANIC ELECTROPHILES
COLLMAN, JP
BROTHERS, PJ
MCELWEEWHITE, L
ROSE, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (21) : 6110 - 6111
[8] CLEAVAGE OF RUTHENIUM AND OSMIUM PORPHYRIN DIMERS - FORMATION OF ORGANOMETALLIC RUTHENIUM PORPHYRIN COMPLEXES AND HIGHLY REDUCED METALLOPORPHYRIN SPECIES
COLLMAN, JP
BROTHERS, PJ
MCELWEEWHITE, L
ROSE, E
WRIGHT, LJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (15) : 4570 - 4571
[9] RADICAL MECHANISM FOR THE DECOMPOSITION OF RUOEP(CH2CH3)2 - DETERMINATION OF THE METAL-CARBON BOND-DISSOCIATION ENERGY
COLLMAN, JP
MCELWEEWHITE, L
BROTHERS, PJ
ROSE, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (06) : 1332 - 1333
[10] REDOX PROPERTIES OF METALLOPORPHYRIN DIMERS
COLLMAN, JP
PRODOLLIET, JW
LEIDNER, CR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (11) : 2916 - 2921

← 1 2 3 →