CRYSTALLIZATION AND STRUCTURE DETERMINATION OF ALKALINE METAL-PARATUNGSTATES

被引：28

作者：

CHRISSAFIDOU, A ^{[1
]}

FUCHS, J ^{[1
]}

HARTL, H ^{[1
]}

PALM, R ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST ANORGAN & ANALYT CHEM,D-14195 BERLIN,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1995年 / 50卷 / 02期

关键词：

PARATUNGSTATES-Z; SYNTHESIS; STRUCTURE DETERMINATION; X-RAY; CATION COORDINATION;

D O I：

10.1515/znb-1995-0211

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and crystal structures of the following paratungstates-Z with different alkaline cations are reported and discussed: Na-10[H2W12O42]. 20 H2O (I), Na-10[H2W12O42]. 27 H2O (II), Na-10[H2W12O42]. 28 H2O (III), K-10[H2W12O42]. 10 H2O (IV), K6Na4[H2W12O42]. 13 H2O (V), Cs6Na4[H2W12O42]. 16 H2O (VI), Cs8Na2[H2W12O42]. 10 H2O (VII), Cs8Na2[H2W12O42]. 12 H2O (VIII), K3Na7[H2W12O42]. 24 H2O (IX) and K8Na2[H2W12O42]. 12 H2O (X). Priority has been set on the description of the coordination of the cations with the oxygen ligands H2W12O4210- and H2O.

引用

页码：217 / 222

页数：6

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