STUDIES ON RUTHENIUM TIN BORIDE CATALYSTS .1. CHARACTERIZATION

被引：54

作者：

DESHPANDE, VM

PATTERSON, WR

NARASIMHAN, CS

机构：

[1] ALCHEM RES CTR,POB 155,BELAPUR RD,THANA 400601,MAHARASHTRA,INDIA

[2] ICI PLC,CHEM & POLYMERS GRP,RUNCORN WA7 4QE,CHESHIRE,ENGLAND

来源：

JOURNAL OF CATALYSIS | 1990年 / 121卷 / 01期

关键词：

D O I：

10.1016/0021-9517(90)90226-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new mixed metal boride catalyst system, RuSnB, was prepared by reducing metal salts with sodium borohydride. The catalysts were also supported on γ-Al2O3. The supported as well as the unsupported catalysts were characterized by H2 chemisorption, XRD, XPS, TEM/EDX, and SIMS techniques. Based on the available evidence from the various techniques, two types of surface species involving Ru, Sn, and B were suggested. © 1990.

引用

页码：165 / 173

页数：9

共 18 条

[1] SUPPORT AND PROMOTER EFFECT OF RUTHENIUM CATALYST .2. RUTHENIUM ALKALINE-EARTH CATALYST FOR ACTIVATION OF DINITROGEN
AIKA, K
OHYA, A
OZAKI, A
INOUE, Y
YASUMORI, I
[J]. JOURNAL OF CATALYSIS, 1985, 92 (02) : 305 - 311
[2] QUANTITATIVE USE OF ANGULAR VARIATION TECHNIQUE IN STUDIES OF TIN BY X-RAY PHOTOELECTRON-SPECTROSCOPY
ANSELL, RO
DICKINSON, T
POVEY, AF
SHERWOOD, PMA
[J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1977, 11 (03) : 301 - 313
[3] STUDIES ON RUTHENIUM TIN BORIDE CATALYSTS .2. HYDROGENATION OF FATTY-ACID ESTERS TO FATTY ALCOHOLS
DESHPANDE, VM
RAMNARAYAN, K
NARASIMHAN, CS
[J]. JOURNAL OF CATALYSIS, 1990, 121 (01) : 174 - 182
[4] PHOTOELECTRON SPECTROSCOPY OF TIN-COMPOUNDS
GRUTSCH, PA
ZELLER, MV
FEHLNER, TP
[J]. INORGANIC CHEMISTRY, 1973, 12 (06) : 1431 - 1433
[5] BIOSYNTHESIS OF CAMPTOTHECIN .3. DEFINITION OF STRICTOSAMIDE AS THE PENULTIMATE BIOSYNTHETIC PRECURSOR ASSISTED BY C-13 AND H-2 NMR-SPECTROSCOPY
HUTCHINSON, CR
HECKENDORF, AH
STRAUGHN, JL
DADDONA, PE
CANE, DE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (12) : 3358 - 3369
[6] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF RUTHENIUM-OXYGEN SURFACES
KIM, KS
WINOGRAD, N
[J]. JOURNAL OF CATALYSIS, 1974, 35 (01) : 66 - 72
[7] EFFICIENT ASYMMETRIC REDUCTION OF ACYL CYANIDES WITH B-3-PINANYL-9-BBN (ALPINE-BORANE)
MIDLAND, MM
LEE, PE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (17) : 3237 - 3239
[8] RU ALUMINA AND RU-MO ALUMINA CATALYSTS - AN XPS STUDY
MITCHELL, PCH
SCOTT, CE
BONNELLE, JP
GRIMBLOT, JG
[J]. JOURNAL OF CATALYSIS, 1987, 107 (02) : 482 - 489
[9] SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES TO UNSATURATED ALCOHOLS OVER MIXED RUTHENIUM TIN BORIDE CATALYSTS
NARASIMHAN, CS
DESHPANDE, VM
RAMNARAYAN, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (02) : 99 - 100
[10] NARASIMHAN CS, 1987, Patent No. 570

← 1 2 →