USE OF HYDROGEN-PEROXIDE AS AN OXYGEN SOURCE FOR INSITU BIODEGRADATION .2. LABORATORY STUDIES

被引:13
作者
AGGARWAL, PK
MEANS, JL
DOWNEY, DC
HINCHEE, RE
机构
[1] Battelle Memorial Institute, Columbus, OH 43201-2693
[2] Engineering Science, Denver
关键词
D O I
10.1016/0304-3894(91)80056-T
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A review of the literature on hydrogen peroxide decomposition and stabilization identified several inorganic and organic compounds that are known to decrease the rate of decomposition of peroxide in simple systems. Phosphate, a commonly used stabilizer in groundwater applications, does not stabilize peroxide in the presence of enzymatic catalysts, primarily catalase, which are the most important catalysts of peroxide decomposition. In laboratory experiments, a variety of other peroxide stabilizers identified in the literature review also did not sufficiently stabilize peroxide. It is concluded that hydrogen peroxide may not be an efficient source of oxygen for in situ bioreclamation processes, at the Eglin Air Force Base, Florida site.
引用
收藏
页码:301 / 314
页数:14
相关论文
共 20 条
[1]  
Hinchee, Downey, Aggarwal, Use of hydrogen peroxide as an oxygen source for in situ biodegradation Part I Field studies, Journal of Hazardous Materials, 28, pp. 287-299, (1991)
[2]  
Britton, Feasibility Studies on the Use of Hydrogen Peroxide to Enhance Microbial Degradation of Gasoline, (1985)
[3]  
Schumb, Satterfield, Wentworth, Hydrogen Peroxide, 128, (1955)
[4]  
George, The specific reactions of iron in some hemoproteins, Adv. Catal., 6, pp. 367-428, (1952)
[5]  
Brown, Jones, Suggett, Recent Developments in the redox chemistry of peroxides, Inorganic Reaction Mechanisms, pp. 159-204, (1970)
[6]  
Walling, Weil, The ferric ion catalysed decomposition of hydrogen peroxide in perchloric acid solutions, International Journal of Chemical Kinetics, pp. 507-516, (1974)
[7]  
Skujins, Extra cellular enzymes in soil, Critical Reviews in Microbiology, pp. 383-422, (1976)
[8]  
Nicholls, Schonbaum, Catalases, Enzymes, 8, pp. 147-226, (1963)
[9]  
Black, Hayon, J. Phys. Chem., 74, pp. 3199-3203, (1970)
[10]  
Beers, Sizer, Sulfide inhibition of catalase, Science, 120, pp. 32-33, (1954)