STUDY OF THE MECHANISM OF HIGHER ALCOHOL SYNTHESIS ON CU-ZNO-AL2O3 CATALYSTS BY CATALYTIC TESTS, PROBE MOLECULES, AND TEMPERATURE PROGRAMMED DESORPTION STUDIES

被引：55

作者：

KIENNEMANN, A ^{[1
]}

IDRISS, H ^{[1
]}

KIEFFER, R ^{[1
]}

CHAUMETTE, P ^{[1
]}

DURAND, D ^{[1
]}

机构：

[1] INST FRANCAIS PETR,F-92506 RUEIL MALMAISON,FRANCE

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1991年 / 30卷 / 06期

关键词：

D O I：

10.1021/ie00054a009

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In addition to catalytic tests, the addition of probe molecules (methanol, formaldehyde, ethylene glycol, ethanol, acetone, propionaldehyde) and thermoprogrammed-desorption studies (formaldehyde, acetaldehyde, ethanol, acetone) have been used to investigate the mechanism of higher alcohol synthesis on Cu-ZnO-Al2O3 catalysts. More attention is given to the first carbon-carbon bond and branched-product formation. An overall mechanism is proposed.

引用

页码：1130 / 1138

页数：9

共 49 条

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