A NEW CLASS OF METAL-SILICON BONDED COMPLEXES - 8-(DIMETHYL-SILYL) QUINOLINE DERIVATIVES OF RHODIUM AND IRIDIUM

被引：13

作者：

DJUROVICH, PI

SAFIR, A

KEDER, N

WATTS, RJ

机构：

[1] Department of Chemistry, University of California at Santa Barbara, Santa Barbara

来源：

COORDINATION CHEMISTRY REVIEWS | 1991年 / 111卷

关键词：

D O I：

10.1016/0010-8545(91)84025-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chelating ligands based upon 8-(dimethylsilyl)quinoline have been synthesized and used to prepare complexes of Rh(III) and Ir(III) in which the ligand coordinates the metal through a combination of M-N and M-Si linkages. These types of complexes have been formed via oxidative addition of the Rh(I) or Ir(I) precursors across either an Si-H or Si-Si bond of the N,Si-chelating ligand, and both bis- and tris-chelated species have been characterized. We report here the first photophysical characterizations of this new class of complexes. Their photophysical properties suggest that substantial modifications, relative to ortho-metalated species, occur as a result of the highly covalent nature of M-Si bonds as compared to M-C bonds.

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页码：201 / 214

页数：14

相关论文

共 41 条

[1] SPECTROSCOPIC (IR, UV-VIS, H-1 AND SN-119 NMR, RESONANCE RAMAN) PROPERTIES OF [(C6H5)3EM(CO)3(ALPHA-DIIMINE)] (M = MN, E = GE, SN, PB, M = RE, E = SN) COMPLEXES AND X-RAY STRUCTURE OF [(C6H5)3SNMN(CO)3(TERT-BU-DAB)] [J].

ANDREA, RR ;

DELANGE, WGJ ;

STUFKENS, DJ ;

OSKAM, A .

INORGANICA CHIMICA ACTA, 1988, 149 (01) :77-84

[2] METAL TO LIGAND CHARGE-TRANSFER PHOTOCHEMISTRY OF METAL-METAL-BONDED COMPLEXES .6. PHOTOCHEMISTRY OF PH3SNM(CO)3(ALPHA-DIIMINE) (M = MN, RE) - EVIDENCE FOR DIFFERENT PRIMARY PHOTOPROCESSES OF THE MN AND RE COMPLEXES [J].

ANDREA, RR ;

DELANGE, WGJ ;

STUFKENS, DJ ;

OSKAM, A .

INORGANIC CHEMISTRY, 1989, 28 (02) :318-323

[3] SYNTHESIS AND COORDINATING PROPERTIES OF 2-PYRIDYLDIMETHYLSILANE [J].

ANG, HG ;

KWIK, WL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 361 (01) :27-30

[4] PHOSPHINOALKYLSILYL COMPLEXES .6. ISOLATION OF A SILYL COMPLEX OF IRIDIUM(I) - CRYSTAL AND MOLECULAR-STRUCTURE OF DICARBONYL(TRIPHENYLPHOSPHINE)-[((DIPHENYLPHOSPHINO)ETHYL)DIMETHYLSILYL]IRIDIUM [J].

AUBURN, MJ ;

GRUNDY, SL ;

STOBART, SR ;

ZAWOROTKO, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (01) :266-267

[5]

AUBURN MJ, 1984, J AM CHEM SOC, V106, P1314, DOI 10.1021/ja00317a024

[6] THE PHOSPHINOMETHYLSILYL GROUP AS A BIFUNCTIONAL BRIDGING LIGAND - X-RAY CRYSTAL-STRUCTURE OF HEXACARBONYLBIS(MU-DIPHENYLPHOSPHINOMETHYLDIMETHYLSILYL)DIRUTHENIUM(II), AND OF ITS REACTION-PRODUCT WITH TRIFLUOROACETIC-ACID, A MONONUCLEAR RUTHENIUM(II) COMPLEX INCORPORATING A UNIQUE COORDINATED SILANOLOM [J].

AUBURN, MJ ;

HOLMESSMITH, RD ;

STOBART, SR ;

ZAWOROTKO, MJ ;

CAMERON, TS ;

KUMARI, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (24) :1523-1525

[7] (PHOSPHINOALKYL)SILYL COMPLEXES .5. SYNTHESIS AND REACTIVITY OF CONGENERIC CHELATE-STABILIZED DISILYL COMPLEXES OF RHODIUM(III) AND IRIDIUM(III) - CHLOROBIS[[(DIPHENYLPHOSPHINO)ETHYL]DIMETHYLSILYL]RHODIUM AND IRIDIUM [J].

AUBURN, MJ ;

STOBART, SR .

INORGANIC CHEMISTRY, 1985, 24 (03) :318-323

[8]

AUBURN MJ, 1984, J CHEM SOC CHEM COMM, P284

[9] SOME ASPECTS OF SILICON-TRANSITION-METAL CHEMISTRY [J].

AYLETT, BJ .

ADVANCES IN INORGANIC CHEMISTRY, 1982, 25 :1-133

[10] SOLAR-ENERGY CONVERSION BY WATER PHOTODISSOCIATION [J].

BALZANI, V ;

MOGGI, L ;

MANFRIN, MF ;

BOLLETTA, F ;

GLERIA, M .

SCIENCE, 1975, 189 (4206) :852-856

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