SYNTHESIS, CHARACTERIZATION AND ELECTROCHEMICAL-BEHAVIOR OF THE [FE4AU(CO)16]N- (N = 1,2,3) CLUSTERS - X-RAY STRUCTURE OF [NME3CH2PH]2[FE4AU(CO)16]CL

被引：19

作者：

ALBANO, VG

AURELI, R

IAPALUCCI, MC

LASCHI, F

LONGONI, G

MONARI, M

ZANELLO, P

机构：

[1] DIPARTIMENTO CHIM FIS & INORGAN,I-40136 BOLOGNA,ITALY

[2] DIPARTIMENTO CHIM,I-53100 SIENA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 19期

关键词：

D O I：

10.1039/c39930001501

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new green [Fe4Au(CO)16]- cluster anion, isolated from the reaction of [Fe3(CO)11]2- with [AuCl4]- salts, displays a bow-tie metal structure similar to that of the [Fe4M(CO)16]2- (M = Pd, Pt) dianions; its chemical and electrochemical reduction sequentially affords the corresponding [Fe4Au(CO)16]2- and [Fe4Au(CO)16]3- anions, the former of which may be considered as a formal d9 gold(II) complex of the [Fe2(CO)8]2- ligand.

引用

页码：1501 / 1502

页数：2

共 23 条

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