SYNTHESIS OF THE FIRST REDOX-ACTIVE ORGANOMETALLIC POLYMERS CONTAINING CYCLOSILOXANES AS FRAMEWORKS

被引：67

作者：

CASADO, CM

CUADRADO, I

MORAN, M

ALONSO, B

LOBETE, F

LOSADA, J

机构：

[1] UNIV AUTONOMA MADRID,FAC CIENCIAS,DEPT QUIM INORGAN,E-28049 MADRID,SPAIN

[2] UNIV POLITECN MADRID,ESCUELA TECN SUPER INGN IND,DEPT INGN QUIM & IND,E-28006 MADRID,SPAIN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 06期

关键词：

D O I：

10.1021/om00006a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new class of ferrocenyl and permethylferrocenyl polymers 2 and 3, containing a cyclotetrasiloxane in the backbone, has been prepared via hydrosilylation reactions. The synthesis of the tetranuclear model 1,3,5,7-tetrakis(ferrocenylethyl)- 1,3,5,7-tetramethylcyclotetrasiloxane (1) is also reported. The different nature of the cyclopentadienyl ring substituents was found to have influence on, the electrochenical behavior of solutions and ofelectrode surfaces modified with electrodeposited films of these polymers.

引用

页码：2618 / 2620

页数：3

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