SYNTHESIS OF BREVICOMIN, PRINCIPAL SEX ATTRACTANT IN FRASS OF FEMALE WESTERN PINE BEETLE

被引：72

作者：

BELLAS, TE

BROWNLEE, RG

SILVERST.RM

机构：

[1] Life Sciences Division Stanford Research Institute, Menlo Park

来源：

TETRAHEDRON | 1969年 / 25卷 / 21期

关键词：

D O I：

10.1016/0040-4020(69)80035-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The sex attractant, brevicomin [exo-7-ethyl-5-methyl-6,8-dioxabicyclo[3.2.1]octane (1)] from the frass of the western pine beetle, Dendroctonus brevicomis, was synthesized through acid catalyzed hydrolysis and cyclization of the cis-epoxide (8). The endo-isomer (2), also present in frass but inactive, was formed on cyclization of the trans-epoxide (9). © 1969.

引用

页码：5149 / &

共 7 条

[1] A SIMPLE PROCEDURE FOR LOCALISATION OF ETHYLENIC BONDS BY MASS SPECTROMETRY [J].