STUDIES ON TENSILE STRENGTH HEAT-SHRINKAGE FORCE AND CRYSTALLINITY OF RAYON TIRE CORDS AND REGENERATED CELLULOSE FILMS AT ELEVATED TEMPERATURES

被引:4
作者
FUKUHARA, S
OMOTE, S
SUZUKI, Y
机构
[1] Research Institute, The Yokohama Rubber Company, Hiratsukashi, Kanagawaken, 150, Shinshuku
关键词
Absorption Spectra; Breaking Strength; Crystallinity; Deuteration; Films; Force; Heat Resistance; Hydrogen Bonds; Infrared Spectra; Rayon (Regenerated Cellulose Fibers); Regenerated Cellulose; Shrinkage; Temperature; Tire Cords;
D O I
10.1177/004051756903900315
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
Measurements were made of tensile strength and heat-shrinkage force of rayon tire cords and of ir absorption spectra (unpolarized and polarized) of regenerated cellulose films in D2O vapor at elevated temperatures. The changes in crystallinity and frequency of OH absorption bands (intermolecular and intramolecular hydrogen bonding) in the crystalline region with increasing temperatures were determined. The ir absorption spectra of dry, regenerated cellulose films were also measured. The decrease in intermolecular hydrogen-bonding force with increasing temperatures was larger than that in intramolecular hydrogen-bonding force in the crystalline region of regenerated cellulose film. The increase in heat-shrinkage force of dry, rayon tire-cord filaments was related with the decrease in hydrogen bonding force. The decrease in tensile strength of rayon tire cord was correlated with the decrease of ir crystallinity and intermolecular hydrogen-bonding force in the crystalline region of regenerated cellulose film. © 1969, SAGE Publications. All rights reserved.
引用
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页码:284 / &
相关论文
共 15 条
[1]   The influence of van der waals' forces and primary bonds on binding energy, strength and orientation, with special reference to some artificial resins. [J].
de Boer, JH .
TRANSACTIONS OF THE FARADAY SOCIETY, 1936, 32 (01) :0010-0036
[2]  
FUKUAHARA S, IN PRESS
[3]  
Hermanns P., 1939, KOLLOID Z, V88, P68, DOI DOI 10.1007/BF01518890
[4]   Article with information on the deformation mechanisms and the structure of hydratecellulose II Deformation mechanism, expansion anisotropy and mechanical characteristics of strong flowing cellulose hydrate gel [J].
Hermans, PH ;
de Leeuw, AJ .
KOLLOID-ZEITSCHRIFT, 1937, 81 (03) :300-326
[5]   Network configuration of welled hydrate cellulose. [J].
Hermans, PH ;
Kratky, O ;
Platzek, P .
KOLLOID-ZEITSCHRIFT, 1939, 86 (02) :245-254
[6]  
HERMANS PH, 1939, KOLLOID Z, V87, P296
[7]  
HERMANS PJ, 1939, KOLLOID Z, V89, P345
[8]  
ILLINGWORTH JW, 1956, TEXT RES J, V26, P243
[9]   THE REACTION BETWEEN CELLULOSE AND HEAVY WATER .3. A QUANTITATIVE STUDY BY INFRA-RED SPECTROSCOPY [J].
MANN, J ;
MARRINAN, HJ .
TRANSACTIONS OF THE FARADAY SOCIETY, 1956, 52 (04) :492-497
[10]   THE REACTION BETWEEN CELLULOSE AND HEAVY WATER .1. A QUALITATIVE STUDY BY INFRA-RED SPECTROSCOPY [J].
MANN, J ;
MARRINAN, HJ .
TRANSACTIONS OF THE FARADAY SOCIETY, 1956, 52 (04) :481-487