PROTONOLYSIS OF THE PT-C BOND IN TRANS-[PTH(CH2CN)(PPH3)2]

被引：39

作者：

UGUAGLIATI, P ^{[1
]}

MICHELIN, RA ^{[1
]}

BELLUCO, U ^{[1
]}

机构：

[1] UNIV VENICE,FAC ENVIRONM HLTH,VENICE,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 169卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81462-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The protonolysis of the PtC bond in trans-[PtH(CH2CN)(PPh32] in methanol/1,2- dichloroethane is shown to take place by a two step mechanism involving oxidative addition to the metal center followed by reductive elimination of CH3CN to give trans-[PtHCl(PPh3)2]. © 1979.

引用

页码：115 / 122

页数：8

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