BETA-INDUCED FLUORESCENCE AS A DETECTION TECHNIQUE FOR LIQUID-CHROMATOGRAPHY .1. PRELIMINARY EXPERIMENTS

被引:16
作者
MALCOLMELAWES, DJ [1 ]
WARWICK, P [1 ]
GIFFORD, LA [1 ]
机构
[1] UNIV MANCHESTER,SCH PHARM,MANCHESTER M13 9PL,LANCASHIRE,ENGLAND
来源
JOURNAL OF CHROMATOGRAPHY | 1979年 / 176卷 / 02期
关键词
D O I
10.1016/S0021-9673(00)85646-0
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A fluorences detector in which 63Ni β-decay radiation is used as exciting source has been constructed and attached to a commercial liquid chromatograph. Pulses of fluorescence emission induced by the β- decays were counted for a number of fluorescent materials in solvents of hexane, toluene and methanol. The detector response was found to be linear over low concentration ranges, although in one instance a marked deviation from linearity was observed at higher concentration. © 1979.
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页码:157 / 163
页数:7
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