RAMAN-SPECTRA OF HALOGEN-SUBSTITUTED METHANES IN THE LIQUID-STATE - DEPOLARIZATION RATIOS OF THE TOTALLY SYMMETRIC VIBRATION BANDS

被引:31
作者
FUKUSHI, K
KIMURA, M
机构
[1] Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo
关键词
D O I
10.1002/jrs.1250080303
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Polarized Raman measurements have been made for the totally symmetric vibration bands of a series of halogen‐substituted methanes in the liquid state at room temperature. The effect of polarization mixing due to divergence was examined experimentally and eliminated. The observed systematic variations in depolarization ratio are discussed in connection with the bond polarizability theory. Copyright © 1979 Heyden & Son Ltd.
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页码:125 / 132
页数:8
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