PROPERTIES OF REDUCED VIOLOGENS IN NAFION FILMS DEPOSITED ON SNO2 ELECTRODES

被引：33

作者：

JOHANSEN, O ^{[1
]}

LODER, JW ^{[1
]}

MAU, AWH ^{[1
]}

RABANI, J ^{[1
]}

SASSE, WHF ^{[1
]}

机构：

[1] CSIRO,DIV CHEM & POLYMERS,CLAYTON,VIC 3168,AUSTRALIA

来源：

LANGMUIR | 1992年 / 8卷 / 10期

关键词：

D O I：

10.1021/la00046a036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optical spectroscopy and cyclic voltammetry were used to study the monomer-dimer equilibrium of the one-electron reduction products of methyl viologen (MV2+), 1-methyl-1'-(3-sulfonatopropyl)-4,4'-bipyridinium (MPVS+), and 1,1'-bis(sulfonatopropyl)-4,4'-bipyridinium (SPV) in Nafion films deposited on SnO2 electrodes. In Nafion the equilibrium constants are considerably smaller than in water and they are affected by the viologen loading.

引用

页码：2577 / 2581

页数：5

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