DETAILED BALANCE FACTORS FOR FREELY ROTATING LINEAR-MOLECULES

被引：6

作者：

STEELE, WA

机构：

[1] Department of Chemistry, Penn State University, PA, 16802, University Park

来源：

MOLECULAR PHYSICS | 1992年 / 76卷 / 05期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1080/00268979200102041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first two even spectral moments for rotational infrared and Raman spectra bands are evaluated exactly for freely rotating linear molecules. Deviations of the second moment from its classical limiting value are evaluated numerically and compared with three approximate expressions for the quantum correction (detailed balance factor) to the classical result.

引用

页码：1265 / 1268

页数：4

共 10 条

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