A CONSTRUCTION PRINCIPLE FOR STABLE MULTIPLY-CHARGED MOLECULAR ANIONS IN THE GAS-PHASE

被引：36

作者：

SCHELLER, MK

CEDERBAUM, LS

机构：

[1] Theoretische Chemie, Physikalisch-Chemisches Institut, Universität Heidelberg, D-69120 Heidelberg

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 216卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(93)E1259-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A construction principle is discussed which allows us to design stable multiply charged molecular anions in the gas phase. A sequence of anionic potassium fluorides with two to seven excess electrons is systematically constructed on the basis of this principle. At the ab initio and ionic model level of theory the stability of these systems to electron detachment and fragmentation is investigated.

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页码：141 / 146

页数：6

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