CRYSTAL AND MOLECULAR-STRUCTURE OF ANTIMONY TRIFLUORIDE TERPYRIDINE 1-1 ADDUCT - A CASE OF PSEUDO-PENTAGONAL-BIPYRAMIDAL GEOMETRY

被引：9

作者：

BATTAGLIA, LP

CORRADI, AB

PELOSI, G

CANTONI, A

ALONZO, G

BERTAZZI, N

机构：

[1] UNIV CAGLIARI,DIPARTIMENTO CHIM & TECNOL INORGAN & METALLORGAN,I-09124 CAGLIARI,ITALY

[2] UNIV PALERMO,DIPARTIMENTO CHIM INORGAN,I-90123 PALERMO,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 11期

关键词：

D O I：

10.1039/dt9910003153

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of SbF3(terpy) (terpy = 2,2':6'2"-terpyridine) has been determined: monoclinic, space group P2(1)/c, with a = 12.511 (2), b = 14.132(3), c = 17.106(3) angstrom, beta = 105.10(1)-degrees; R = 0.0434. The asymmetric unit contains two independent molecules which show only small differences: each contains a terpy molecule, two fluorines nearly accommodated in a plane and a fluorine at the apical site of a pseudo-pentagonal-bipyramidal arrangement in which the seventh position is occupied by the antimony lone pair.

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页码：3153 / 3155

页数：3

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