KINETICS OF CATALYTIC ETHANE HYDROGENOLYSIS - STIRRED REACTOR STUDY OF COMMERCIAL NICKEL CATALYST

被引：13

作者：

TAJBL, DG

机构：

[1] Institute of Gas Technology, Chicago, Illinois

[2] Mobil Oil Corporation, Paulsboro, New Jersey

来源：

CANADIAN JOURNAL OF CHEMICAL ENGINEERING | 1969年 / 47卷 / 02期

关键词：

D O I：

10.1002/cjce.5450470209

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetics of ethane hydrogenolysis catalyzed by a commercial 58% nickel‐on‐kieselguhr catalyst were studied at 1 atm. and from 220° to 250°C. The kinetic data could be fit by a simple power rate equation that is a limiting case of a more general equation. The reaction rate of ethane was first order with respect to ethane and —2 order with respect to hydrogen. A possible reaction mechanism is discussed. The apparent activation energy was 46.4 kcal. Ethane/hydrogen ratios as high as 1:1 were studied without catalyst deactivation. Kinetic data were obtained in a novel stirred‐tank catalytic reactor. Copyright © 1969 Canadian Society for Chemical Engineering

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页码：154 / &

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