Laser-Raman spectra and hindered rotation in the phosphonium halides

被引：6

作者：

Rush, J. J. ^{[1
]}

Merlveger, A. J.

Farrar, T. C.

Tsang, Tung

机构：

[1] Natl Bur Stand, Ctr Radiat Res, Washington, DC USA

[2] Univ Maryland, Dept Chem, College Pk, MD 20742 USA

[3] Univ Maryland, Ctr Mat Res, College Pk, MD 20742 USA

[4] Natl Bur Stand, Inst Mat Res, Washington, DC USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 08期

关键词：

D O I：

10.1016/0009-2614(63)80034-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Laser-Raman spectra have been measured for PH4Cl, PH4Br and PH4I. Intense peaks in all the halide spectra are assigned to torsional (E-g) oscillations and to the internal vibrations of the PH4- ions. Barriers to PH4- rotation are calculated and lscussed in comparison with recent spectroscopic an structural results.

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页码：621 / 624

页数：4

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