SPECTRAL AND ENERGY DATA FOR BIS (POLYFLURO-ARYL) AMINE COMPLEXES WITH HYDROGEN NH...B BOND

被引：7

作者：

BORISENKO, VE

MAXIMOV, EV

DENISOV, GS

FURIN, GG

ZAVJALOVA, JA

机构：

[1] ST PETERSBURG STATE UNIV, INST PHYS, ST PETERSBURG 198904, RUSSIA

[2] NOVOSIBIRSK INST ORGAN CHEM, NOVOSIBIRSK 680090, RUSSIA

来源：

SPECTROSCOPY LETTERS | 1993年 / 26卷 / 06期

关键词：

IR SPECTROSCOPY; HYDROGEN BOND; BIS (POLYFLUORO-ARYL) AMINE; ENTHALPY OF HYDROGEN BONDS;

D O I：

10.1080/00387019308011599

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

In the IR spectra of complexes of (C6F5)2NH, (4-CF3C6F4)2NH and (gamma-NC5F4)2NH with acetonitrile, tetrahydrofurane, dimethylformamide, dimethylsulfoxide and hexametapole, the nu(NH) band has a complex structure due to Fermi resonance with low-frequency vibration combinations. In the range of 15-65-degrees-C the equilibrium constants and complex formation enthalpies in CCl4 solution have been determined.

引用

页码：1139 / 1151

页数：13

共 13 条

[1] TEMPERATURE EFFECTS ON INDOLE AND PYRROLE NU(N-H) ABSORPTION-BANDS IN H-BONDED COMPLEXES [J].