SYNTHESIS, CHARACTERIZATION AND FLUXIONAL BEHAVIOR OF [NI(ETA(5)-P(2)C(3)BU(3)(T))(ETA(3)-P(2)C(3)BU(3)(T))]

被引：21

作者：

CLOKE, FGN ^{[1
]}

FLOWER, KR ^{[1
]}

JONES, C ^{[1
]}

MATOS, RM ^{[1
]}

NIXON, JF ^{[1
]}

机构：

[1] UNIV FED MINAS GERAIS,ICEX,DEPT QUIM,BR-31270901 BELO HORIZONT,MG,BRAZIL

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期

关键词：

NICKEL; POLYPHOSPHOLYL LIGANDS; FLUXIONALITY; RING SLIPPAGE;

D O I：

10.1016/0022-328X(94)05128-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of either [Na(DME)(3)][P(2)C(3)Bu(3)(t)] or [Yb(P(2)C(3)Bu(3)(t))(2)] with [NiBr2(DME)(2)] affords the title compound which displays eta(5)-eta(3)-''ring slippage'' behaviour in solution.

引用

页码：C21 / C23

页数：3

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