SYNTHESIS OF SYN AND ANTI HOMOPROPARGYLIC AND ALLENIC ALCOHOLS THROUGH DIASTEREOSELECTIVE S(E)2' ADDITION OF A COMMON CHIRAL ALLENYLSTANNANE PRECURSOR TO ALDEHYDES

被引：47

作者：

MARSHALL, JA

PERKINS, J

机构：

[1] Department of Chemistry and Biochemistry, University of South Carolina, Columbia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 13期

关键词：

D O I：

10.1021/jo00092a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The (tri-n-butylallenyl)stannanes 3 and 17 afford the allenyl adducts 8 and 19 upon brief treatment with stannic chloride and then addition of isobutyraldehyde, whereas preequilibration with SnCl4 and subsequent aldehyde addition leads to the anti homopropargylic adducts 5 and 19.

引用

页码：3509 / 3511

页数：3

共 14 条

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