CHARGE-TRANSFER SALTS BASED ON BET-TTF AND THE LINEAR IONS AUX(2)(-) (X=BR, I)

被引：13

作者：

ROVIRA, C ^{[1
]}

VECIANA, J ^{[1
]}

TARRES, J ^{[1
]}

MOLINS, E ^{[1
]}

MAS, M ^{[1
]}

COWAN, DO ^{[1
]}

YANG, S ^{[1
]}

机构：

[1] JOHNS HOPKINS UNIV,DEPT CHEM,BALTIMORE,MD 21218

来源：

SYNTHETIC METALS | 1995年 / 70卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)02690-Z

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The organic pi-electron donor E-bis(ethylenethio)-tetrathiafulvalene (BET-TTF) forms several charge-transfer salts with linear AuX(2)(-) (X = Br, I) counterions. Experimental conditions significantly affect the shape and the composition of the charge-transfer crystals. In fact, salts with different stoichiometries are obtained from each counterion. The magnetic behavior of the obtained salts have been studied by EPR spectroscopy. The EPR parameters (g, and Delta H-pp) of different mixed valence salts with the same counterion are very similar. The crystal structure of (BET-TTF)AuBr2 has been determined by X-Ray diffraction: triclinic system, P-1, Z=1, a=5.790(4)Angstrom, b = 7.786(3)Angstrom, c=9.716(8)Angstrom, alpha=75.11(5)degrees, beta=89.30(4)degrees, gamma=77.20(5)degrees, V=395.5(5)Angstrom(3). Single crystal electrical conductivity measurements of (BET-TTF)(2)AuBr2, show that this salt exhibits a semiconducting behavior with a sigma(300)=1.1 Scm(-1) and an energy gap of 0.14 eV.

引用

页码：883 / 886

页数：4

共 16 条

[1] VIBRATIONAL SPECTROSCOPY OF MOLECULAR CONSTITUENTS OF ONE-DIMENSIONAL ORGANIC CONDUCTORS - TETRATHIOFULVALENE (TTF), TTF+, AND (TTF+)2 DIMER [J].