ALKALINE-METALS .20. SYNTHESIS AND REACTIVITY OF C6ME6RU(CO)PM3 - STABLE AROMATIC RUTHENIUM(O) CARBONYL COMPLEX

被引：27

作者：

WERNER, H

WERNER, R

机构：

[1] Institut für Anorganische Chemie der Universität Wurzbürg, D-8700 Würzburg, Am Hubland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)85607-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [C6Me6RuCl2]2 with carbon monoxide gives C6Me6Ru(CO)Cl2 (II) which reacts with PMe3 in the presence of NH4PF6 to form [C6Me6Ru(CO)(PMe3)Cl]PF6 (III). Reduction of the cation of III with NaC10H8 in THF yields C6Me6Ru(CO)PMe3 (IV) which is the first stable mononuclear areneruthenium(0) carbonyl complex. IV reacts with CF3COOH/NH4PF6 and MeI/NH4PF6 to give the stable salts [C6Me6RuH(CO)PMe3]PF4 (V) and [C6Me6RuCH3(CO)PMe3]PF6 (VI). © 1979.

引用

页码：C67 / C69

页数：3

共 5 条

[1] BASIC METALS .16. INTERCONVERSION OF ALKYL-COBALT(III) AND ACYL-COBALT(III) COMPLEXES DERIVED FROM CYCLOPENTADIENYLCARBONYL(TRIMETHYLPHOSPHINE)COBALT(I) [J].