SPIN-INVERSION AND ORBITAL SYMMETRY CONSPIRACY IN TYPE-A LUMIKETONE REARRANGEMENTS

被引：32

作者：

SHAIK, SS

机构：

[1] Department of Chemistry, Cornell University Ithaca, New York

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 10期

关键词：

D O I：

10.1021/ja00504a044

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Type A lumiketone rearrangement is known to originate from a triplet state1, 2 with evidence suggesting a 3ππ* reactive state. 2b-d The reaction (I) can be viewed as a formal [2π + 2σ]. © 1979, American Chemical Society. All rights reserved.

引用

页码：2736 / 2738

页数：3

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