CHARGE-TRANSFER SPECTRA OF PERMETHYLATED POLYGERMANES TCNE TO AFFORD 1-1 ADDUCTS

被引：45

作者：

MOCHIDA, K ^{[1
]}

HODOTA, C ^{[1
]}

HATA, R ^{[1
]}

FUKUZUMI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 02期

关键词：

D O I：

10.1021/om00026a052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Charge-transfer spectra of permethylated polygermane-tetracyanoethylene (TCNE) complexes were observed. The frequency of charge-transfer spectra was linearly related to ionization potentials (or electrochemical oxidation potentials) of the polygermanes. Polygermanes inserted into TCNE to afford 1:1 adducts under mild conditions.

引用

页码：586 / 588

页数：3

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