NOVEL DIMERIC STRUCTURE IN THE PD(II) COMPLEX OF 1,10-DITHIA[2](2,6)PYRIDINO[2](1,1')FERROCENOPHANE - A CONNECTED METAL-METAL INTERACTION

被引：14

作者：

SATO, M ^{[1
]}

ASANO, H ^{[1
]}

AKABORI, S ^{[1
]}

机构：

[1] TOHO UNIV,FAC SCI,DEPT CHEM,FUNABASHI,CHIBA 274,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 452卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83179-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Pd(BF4)2 complex of 1,10-dithia[2](2,6)pyridino[2](1,1')ferrocenophane was prepared. The NMR spectral data suggested that the complex has a weak dative bond between the Pd and Fe atoms. The X-ray analysis of the complex supported the suggestion and also showed that a weak Pd-Pd bonding interaction connects two molecules, resulting in a novel dimeric structure.

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页码：105 / 109

页数：5

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