STRUCTURE-FREQUENCY CORRELATIONS - ANALYZING NON-ADDITIVE DATA PATTERNS OF SATURATED ALIPHATIC-ALCOHOLS - EXAMPLE

被引：2

作者：

CREESE, MW ^{[1
]}

CREESE, TM ^{[1
]}

机构：

[1] UNIV KANSAS,DEPT MATH,LAWRENCE,KS 66045

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1979年 / 52卷 / 02期

关键词：

D O I：

10.1016/0022-2860(79)80123-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The OH stretching frequencies, νmax values, for a series of 22 monohydric, saturated, aliphatic alcohols have been examined, and a structure-frequency correlation pattern is presented. A formal procedure is offered for analyzing frequency differences (and contrasts), and it is shown that the frequency pattern for the majority of the compounds is well described by a simple, non-linear formula. It is concluded that the substituent effects are non-additive. © 1979.

引用

页码：253 / 273

页数：21

共 17 条

[1]

ALBRITTON DL, 1976, MOL SPECTROSCOPY MOD, V2, P1

[2]

BELLAMY LJ, 1962, SPECTROSCOPY REP C O, P220

[3] STATISTICAL-METHODS FOR COMBINING AND IMPROVING CHEMICAL-DATA TAKEN FROM SEVERAL INDEPENDENT SOURCES [J].