STUDIES ON SELECTIVE NUCLEOPHILIC-SUBSTITUTION REACTIONS OF [(CYCLOPENTADIENYL)(1,3-DICHLOROBENZENE)M]+ PF6(-) COMPLEXES (M = FE, RU)

被引：56

作者：

PEARSON, AJ

PARK, JG

ZHU, PY

机构：

[1] Department of Chemistry, Case Western Reserve University, Cleveland

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 13期

关键词：

D O I：

10.1021/jo00039a015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of [cyclopentadienyl)(1,3-dichlorobenzene)M]+PF6- complexes (M = Fe, Ru) with phenoxide nucleophiles were found to proceed with excellent selectivity under mild conditions to give products of monosubstitution. Using aminophenoxides, a preference for O-arylation was observed, while amino alcohols such as prolinol react selectively on nitrogen. Methodology for sequential selective displacement of both chlorides by different nucleophiles is reported.

引用

页码：3583 / 3589

页数：7

共 43 条

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