SINGLE ELECTRON-TRANSFER IN THE ADDITION OF CHIRAL DIPOLE-STABILIZED ORGANOLITHIUMS TO CARBONYLS - STEREOCHEMISTRY OF A CHIRAL NUCLEOPHILE AS A MECHANISTIC PROBE

被引：23

作者：

REIN, KS ^{[1
]}

CHEN, ZH ^{[1
]}

PERUMAL, PT ^{[1
]}

ECHEGOYEN, L ^{[1
]}

GAWLEY, RE ^{[1
]}

机构：

[1] UNIV MIAMI,DEPT CHEM,CORAL GABLES,FL 33124

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 17期

关键词：

D O I：

10.1016/0040-4039(91)85007-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Spectroscopic and stereochemical evidence is provided which suggests that single electron transfer (SET) accounts for the difference in selectivity observed in the reaction of metalated pivalamides and oxazolines with carbonyls.

引用

页码：1941 / 1944

页数：4

共 25 条

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