CHARACTERIZATION OF TRIMETHYLOL PHENOL BY THERMAL-ANALYSIS

被引：3

作者：

GOSWAMI, TH ^{[1
]}

MAITI, MM ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KHARAGPUR 721302,W BENGAL,INDIA

来源：

THERMOCHIMICA ACTA | 1992年 / 197卷 / 02期

关键词：

D O I：

10.1016/0040-6031(92)85046-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A study was made of the condensation and thermal behaviour of trimethylol phenol (TMP) as a model of a phenol-formaldehyde (PF) resin. Results of study by the combined techniques of differential thermal analysis and thermogravimetry, without resorting to spectroscopic or chromatographic methods, clearly corroborate existing theories regarding the mechanism of curing of PF resins, but in addition it proved possible to attempt a quantitative evaluation of the thermoanalytical behaviour of TMP in air. The relative reactivities of 2,2'-, 2,4'- and 4,4'-dimethylene ethers in their decomposition to methylene bridges are shown to decrease in the order 4,4'- > 2,4'- > 2,2'-. It is concluded that the purity and/or identity of any methylol phenol can be established by conventional combined DTA-TG measurements.

引用

页码：453 / 462

页数：10

共 16 条

[1]

CONLEY RT, 1963, J APPL POLYM SCI, V7, P171

[2]

CONLEY RT, 1963, J APPL POLYM SCI, V7, P105

[3]

Dyer JR, 1987, APPLICATIONS ABSORPT

[4]

EULER HV, 1942, CHEM ABSTR 7184, V36

[5]

Hultzsch K., 1950, CHEM PHENOLHARZE

[6]

Jackson WM., 1964, J APPL POLYM SCI, V8, P2163, DOI DOI 10.1002/APP.1964.070080516

[7]

KRAMMERER H, 1966, GER PLAST, V56, P1

[8]

MEYERS CY, 1959, Patent No. 2889374

[9]

MILLANE JJ, 1963, PLASTICS LONDON, V28, P101

[10]

MILLANE JJ, 1964, PLASTICS LOND, V29, P81

← 1 2 →