EASILY REVERSIBLE IONIC FRAGMENTATION OF A TETRAHEDRAL UNSATURATED RHENIUM CLUSTER, A REAPPRAISAL OF THE REACTION OF [RE-4(MU(3)-H)(4)(CO)(12)] WITH METHANOL

被引：14

作者：

BERINGHELLI, T ^{[1
]}

DALFONSO, G ^{[1
]}

机构：

[1] CTR CNR,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,I-20133 MILAN,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 22期

关键词：

D O I：

10.1039/c39940002631

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unsaturated tetrahedral cluster [Re-4(mu(3)-H)(4)(CO)(12)] in the presence of weak donor molecules L, like methanol or acetone, reversibly fragments to unsaturated triangular cluster anions and to mononuclear cations, probably via spiked-triangular [Re-4(mu-H)(4)(CO)(12)L(4)] intermediates.

引用

页码：2631 / 2632

页数：2

共 14 条

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