ACID-RAIN AND SOILS OF THE ADIRONDACKS .3. RATES OF SOIL ACIDIFICATION IN A MONTANE SPRUCE-FIR FOREST AT WHITEFACE MOUNTAIN, NEW-YORK

To assess the impact of atmospheric deposition on soil acidification and base cation supplies in montane spruce-fir forest soils at Whiteface Mountain, New York, base cation and proton fluxes were determined for organic and mineral horizons from measurements made at four stands (1020-1090 m above sea level) over a 4-year period. Our best estimates indicate an annual accumulation of H+ and a net loss of base cations from the forest floor of about 0.71 kmol(c)/ha, a 2.8% per year loss of the total forest floor base cation pool. This high rate of acidification is attributable to base cation leaching by sulfate and organic anions, and uptake by living biomass. From 1986 to 1990, the annual net loss rate of forest floor Ca, the most abundant base cation, was several times greater than historical loss rates as determined by 50-year comparisons of forest floor Ca in nearly identical forests of the Adirondack High Peaks region. Published data on long-term trends in Ca deposition in the U.S. Northeast suggest that the difference between historical and current net loss rates of forest floor Ca may be due to sharply reduced atmospheric inputs of Ca after about 1970, exacerbated by sulfate leaching. In mineral horizons where the total base cation pool (mostly mineral bound) is very large, the net losses of base cations were substantially lower and in the range where losses due to leaching and uptake can be countered by mineral weathering.