NQR ZEEMAN STUDY OF GALLIUM TRICHLORIDE

被引：23

作者：

PETERSON, GE

BRIDENBAUGH, PM

机构：

[1] Bell Telephone Laboratories, Incorporated, Murray Hill

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 01期

关键词：

D O I：

10.1063/1.1671713

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An NQR Zeeman study of a single crystal of gallium trichloride is made. The electric-field-gradient asymmetry parameters and major field-gradient directions for all atoms in the dimer molecule are obtained. The asymmetry parameters for the gallium and the bridge chlorines are quite large, being 0.867 and 0.473, respectively. An analysis of the data, based on the theory of Casabella, suggests the possibility of bent bonds.

引用

页码：238 / +

页数：1

共 11 条

[1]

Akishin P.A., 1959, KRISTALLOGRAFIYA, V4, P194

[2]

BRIDENBAUGH PM, UNPUBLISHED

[3]

Buckley H.E., 1951, CRYSTAL GROWTH

[4] ELECTRONIC STRUCTURE OF SOME GROUP-III HALIDES FROM PURE QUADRUPOLE RESONANCE MEASUREMENTS [J].