THE PREPARATION OF THE 2,4-DI(TERT-BUTYL)PENTADIENYL ANION AND ITS TI(II), CR(II), AND ZN(II) COMPLEXES

被引：32

作者：

ERNST, RD ^{[1
]}

FREEMAN, JW ^{[1
]}

SWEPSTON, PN ^{[1
]}

WILSON, DR ^{[1
]}

机构：

[1] MOLEC STRUCT CORP, THE WOODLANDS, TX 77381 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 402卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-328X(91)80077-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The postassium salt of the 2,4-di(t-butyl)pentadienyl anion may be prepared by metallation of the corresponding 1,3-diene. This anion reacts readily with titanium, chromium, and zinc dichloride complexes to yield the appropriate M[2,4-(t-C4H9)2C5H5]2 species, which display significant differences relative to their 2,4-dimethylpentadienyl analogs.

引用

页码：17 / 25

页数：9

共 33 条

[1]

[Anonymous], ORGANOMET SYNTH

[2]

CAMPANA CF, 1984, INORG CHEM, V23, P2732

[3] SYNTHESES, REACTIVITIES, MOLECULAR-STRUCTURES, AND PHYSICAL-PROPERTIES OF PARAMAGNETIC BIS(TETRAPHENYLCYCLOPENTADIENYL) COMPLEXES OF VANADIUM, CHROMIUM, COBALT, AND NICKEL [J].