STEPWISE AND REVERSIBLE CLEAVAGE OF THE C-O DOUBLE-BOND OF DIARYL KETONES BY LANTHANIDE METALS

被引：58

作者：

HOU, ZM

YAMAZAKI, H

FUJIWARA, Y

TANIGUCHI, H

机构：

[1] HIROSHIMA UNIV,FAC ENGN,DEPT APPL CHEM,HIGASHIHIROSHIMA 724,JAPAN

[2] KYUSHU UNIV,FAC ENGN,DEPT CHEM SCI & TECHNOL,FUKUOKA 812,JAPAN

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 07期

关键词：

D O I：

10.1021/om00043a069

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of diaryl ketones with excess lanthanide (Ln = Sm, Yb) metals caused the complete cleavage of their C-O double bonds. This C-O bond-cleavage process was stepwise and reversible and was possibly mediated by a mu-oxo, mu-alkylidene complex.

引用

页码：2711 / 2714

页数：4

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