ASYMMETRIC DIHYDROXYLATION OF GERANYL, NERYL AND TRANS,TRANS-FARNESYL ACETATES

被引：73

作者：

VIDARI, G

DAPIAGGI, A

ZANONI, G

GARLASCHELLI, L

机构：

[1] Dipartimento di Chimica Organica - Universita' di Pavia -, 27100 Pavia

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 40期

关键词：

D O I：

10.1016/0040-4039(93)85077-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The asymmetric dihydroxylation of geranyl acetate, neryl acetate and trans, trans -farnesyl acetate was studied using the new Sharpless' ligands (DHQD)2-PHAL and (DHQ)2-PHAL. High enantioselectivity was always observed. High positional selectivity for the 6,7-olefin was observed in the case of the monoterpene acetates.

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页码：6485 / 6488

页数：4

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