Synthesis and base promoted intramolecular nucleophilic reaction of 8-hydroxy-1,2,3,4-tetrachloro-9,9-dimethoxy-1 alpha,4 alpha,4a alpha,6,7,8 beta,8a alpha-hexahydro-1,4-methanonaphthalene-5(1H)-one

被引：2

作者：

Bott, SG ^{[1
]}

Marchand, AP ^{[1
]}

Bolin, JC ^{[1
]}

Wang, YJ ^{[1
]}

Prasad, AD ^{[1
]}

Xing, DX ^{[1
]}

Talafuse, LK ^{[1
]}

Watson, WH ^{[1
]}

Bourne, SA ^{[1
]}

Carlson, TF ^{[1
]}

机构：

[1] TEXAS CHRISTIAN UNIV,DEPT CHEM,FT WORTH,TX 76129

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1995年 / 25卷 / 10期

关键词：

crystal structures; hexahydro-1,4-methanonaphthalene; reduction;

D O I：

10.1007/BF01665970

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Catalytic hydrogenation of two substituted hexahydro-1,4-dimethanonaphthalene-5,8-diones results in reduction of the enedione carbon-carbon double bond with concomitant reduction of only one of the two chemically equivalent C = O groups. Reaction of one partially reduced product with base results in intramolecular addition to the carbon-carbon double bond.

引用

页码：641 / 651

页数：11

共 28 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].