PERHYDROINDAN DERIVATIVES .11. 7-METHOXYHEXAHYDROFLUORENE SYSTEM

被引:24
作者
HOUSE, HO
BARE, TM
HANNERS, WE
机构
[1] Department of Chemistry, Massachusetts Institute of Technology, Cambridge
关键词
D O I
10.1021/jo01259a040
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The known methoxyhexahydrofluorenone 6 has been converted into acids 1-4 desired as models for study of transformations in the aromatic ring. Of the various methods used to introduce the carboxyl functions, the selective lithium-hydrogen exchange and subsequent carbonation reactions applied to the olefins 10 and 35 and to alcohol 8 are worthy of special note. © 1969, American Chemical Society. All rights reserved.
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页码:2209 / &
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