A FLUORINE-19 NUCLEAR MAGNETIC RESONANCE STUDY OF SOME TITANIUM TETRAFLUORIDE-SUBSTITUTED PYRIDINE 1-OXIDE ADDUCTS

被引：42

作者：

DYER, DS

RAGSDALE, RO

机构：

[1] Air Force Materials Laboratory, Wright-Patterson Air Force Base, Dayton

[2] Department of Chemistry, University of Utah, Salt Lake City

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 05期

关键词：

D O I：

10.1021/ic50075a019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A fluorine-19 nmr study of several substituted pyridine 1-oxide adducts of titanium tetrafluoride is reported. Evidence for the existence of a number of trans-TiF4.2(donor) complexes is presented and discussed. Mixed adducts of TiF4 in which the donor molecules are oriented trans to each other in solution are reported for the first time. The factors which determine the stereochemistry of the TiF4.2(donor) complexes are discussed. It appears that trans-TiF4.2(donor) is formed only when there is sufficient steric interaction to overcome symmetry effects and the tendency to maximize pπ-dπ bonding. © 1969, American Chemical Society. All rights reserved.

引用

页码：1116 / &

共 11 条

[1] THE ACCEPTOR PROPERTIES OF QUADRIPOSITIVE SILICON, GERMANIUM, TIN, AND LEAD [J].