SOME SUBSTITUTION REACTIONS OF NIOBIUM(IV) HALIDES

被引：12

作者：

MACHIN, DJ

SULLIVAN, JF

机构：

[1] Department of Chemistry, The University, Manchester

来源：

JOURNAL OF THE LESS-COMMON METALS | 1969年 / 19卷 / 04期

关键词：

D O I：

10.1016/0022-5088(69)90186-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions of niobium(IV) chloride, bromide and iodide with potassium thiocyanate, cyanate, cyanide, and borohydride; sodium diethyldithiocarbamate, and N,N′-bis (salicylidene) ethylenediammine have been investigated. Complete replacement of halide occurs only in the case of the reaction with sodium diethyldithiocarbamate, other reactions leading to complex stoichiometries. The magnetic, and vibrational and electronic spectral properties of the products are described. © 1969.

引用

页码：413 / &

共 28 条

[1] CRYSTAL STRUCTURE OF NITROSO(DIMETHYLDITHIOCARBONATO)COBALT [CO(NO)[S2C.N(CH3)2]2] [J].

ALDERMAN, PR ;

ROWE, JM ;

OWSTON, PG .

JOURNAL OF THE CHEMICAL SOCIETY, 1962, (FEB) :668-&

[2]

BRADLEY DC, 1965, CHEM COMMUN, P289

[3]

BROWN DM, PERSONAL COMMUNICATI

[4] REACTIONS OF NIOBIUM TETRAHALIDES WITH SOME TERTIARY AMINES [J].

BROWN, TM ;

NEWTON, GS .

INORGANIC CHEMISTRY, 1966, 5 (07) :1117-&

[5] NIOBIUM(V) AND TANTALUM(V) HEXAISOTHIOCYANATES [J].

BROWN, TM ;

KNOX, GF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (20) :5296-&

[6]

Chatt J., 1956, SUOMEN KEMI B, V29, P75

[7]

CHUANG YY, 1960, VESTN MOSKOV U 2, V15, P40

[8] 8-CO-ORDINATE DIARSINE COMPLEXES OF QUADRIVALENT METAL HALIDES [J].

CLARK, RJ ;

LEWIS, J ;

NYHOLM, RS ;

PAULING, P ;

ROBERTSO.GB .

NATURE, 1961, 192 (479) :222-&

[9]

CLARK RJH, 1965, J CHEM SOC, P2863

[10]

DEATSCHER RL, 1969, J CHEM SOC D, P121

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