SYNTHESIS AND MOLECULAR-STRUCTURES OF DIFERROUS COMPLEXES CONTAINING A BIS(HYDROXO) OR A HYDROXO CARBOXYLATO BRIDGE

被引:69
作者
KITAJIMA, N
TAMURA, N
TANAKA, M
MOROOKA, Y
机构
关键词
D O I
10.1021/ic00042a002
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis, characterization, and X-ray structures of novel diferrous complexes containing a bis(mu-hydroxo) (2) or a mu-hydroxo mu-carboxylato (3) bridge are presented. Both 2 and 3 possess open coordination sites and react with dioxygen at low temperature, to give dark green complexes, possibly dioxygen adducts, whose structures have not yet been unambiguously determined. [GRAPHICS]
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页码:3342 / 3343
页数:2
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