A NEW APPROACH TO PIPERIDINE ALKALOIDS - AN ENANTIOSELECTIVE TOTAL SYNTHESIS OF (2S,6R)-DIHYDROPINIDINE AND (2R,6S)-DIHYDROPINIDINE

被引：45

作者：

LU, ZH ^{[1
]}

ZHOU, WS ^{[1
]}

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 05期

关键词：

D O I：

10.1039/p19930000593

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An enantioselective total synthesis of (2S,6R)- and (2R,6S)-dihydropinidine, utilizing the (2R,6R)-1,6-dihydro-6-hydroxy-2-methyl-N-tosyl-pyridin-3(2H)-one 3 and its enantiomer 3' obtained from kinetic resolution of alpha-furfuryl amide 2 by modified Sharpless asymmetric epoxidation as starting material, is described.

引用

页码：593 / 596

页数：4

共 23 条

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