ELECTROLUMINESCENCE FROM POLYOLEFINS SUBJECTED TO A HOMOGENEOUS AC FIELD

Electroluminescence associated with ac voltage aging of polyolefins has been reported under divergent field configuration. Neither the mechanism of excitation nor the nature of luminescent centers are well understood in these polymers. Homogeneous field experiments are desirable since they are easier to run and more light can be collected, thereby allowing spectral analysis to be made. We describe a suitable experimental configuration for electroluminescence detection from polyethylene and polypropylene films submitted to a homogeneous field and report on surface roughness, field, and time dependence of the light emission. Field and time dependence of the light spectra are also investigated. It is shown that the light originates from the polymer bulk and is controlled by the surface roughness of the films. The light spectrum appears to consist of two components which exhibit different behavior as a function of field and stressing time. A tentative explanation is given in terms of competition between two different excitation processes.