X-RAY DIFFRACTION STUDIES OF MONO- AND POLYNUCLEAR THORIUM(IV) IONS IN AQUEOUS PERCHLORATE SOLUTIONS

被引：14

作者：

BACON, WE

BROWN, GH

机构：

[1] Department of Chemistry, Kent State University, Kent

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 12期

关键词：

D O I：

10.1021/j100846a022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

X-ray diffraction study of aqueous solutions of thorium (IV) oxyperchlorate has established the presence of polynuclear species containing clusters of four thorium atoms. The thorium-thorium distance is 4.00 Å. Thorium(IV) perchlorate in acid media is found to contain mononuclear species. The thorium(IV) has a coordination number of 11 in both thorium(IV) oxyperchlorate and thorium(IV) perchlorate solutions.

引用

页码：4163 / &

共 23 条

[1]

BEWELOGUA L, 1931, PHYS Z, V32, P740

[2] A TABLE OF DISPERSION CORRECTIONS FOR X-RAY SCATTERING OF ATOMS [J].