SIGMA-5-BORYLCYCLOPENTADIENYLTITANIUM(V) COMPLEXES

被引：43

作者：

JUTZI, P

SEUFERT, A

机构：

[1] Institut für Anorganische Chemie der Universität

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 169卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)80976-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Borylcyclopentadienyl-trimethylsilanes react with titaniumtetrachloride under cleavage of the CSi bond to the η5-borylcyclopentadienyl-titanium(IV)trichlorides I-V. The dichloroboryl complex I can be converted to the dimethylborylcomplex VI by reaction with tetramethylstannane. The 1H-, 13C- and 11B-n.m.r.spectra of the new compounds are described. © 1979.

引用

页码：373 / 380

页数：8

共 13 条

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