THE IMPORTANCE OF PERIODIC-ORBITS IN ANALYZING PHOTODISSOCIATION RESONANCES - THE O3 CASE

被引：24

作者：

FARANTOS, SC ^{[1
]}

机构：

[1] FORTH,INST ELECTR STRUCT & LASER,GR-71110 IRAKLION,GREECE

来源：

CHEMICAL PHYSICS | 1992年 / 159卷 / 03期

关键词：

D O I：

10.1016/0301-0104(92)87060-M

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Time-dependent quantum mechanical and classical trajectory calculations have been performed for ozone in the electronically excited state, 1B2, and with the bending mode frozen. Contrary to what was previously believed, it is shown that the 2D quantum autocorrelation function has an oscillatory structure, which can be analysed by finding the periodic orbits above the barrier of isomerization.

引用

页码：329 / 338

页数：10

共 32 条

[1] FLUORESCENCE AND STIMULATED-EMISSION S1-]SO SPECTRA OF ACETYLENE - REGULAR AND ERGODIC REGIONS
ABRAMSON, E
FIELD, RW
IMRE, D
INNES, KK
KINSEY, JL
[J]. JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (02) : 453 - 465
[2] 3-DIMENSIONAL ANALYTICAL MODEL FOR THE PHOTODISSOCIATION OF SYMMETRICAL TRIATOMICS - ABSORPTION AND FLUORESCENCE-SPECTRA OF OZONE
ATABEK, O
BOURGEOIS, MT
JACON, M
[J]. JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (12) : 6699 - 6711
[3] INFRARED-SPECTRA OF 16O3 AND 18O3 - DARLING AND DENNISON RESONANCE AND ANHARMONIC POTENTIAL FUNCTION OF OZONE
BARBE, A
SECROUN, C
JOUVE, P
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1974, 49 (02) : 171 - 182
[4] BISSELING RH, 1985, J CHEM PHYS, V83, P993, DOI 10.1063/1.449426
[5] PHOTOABSORPTION AND PHOTOEMISSION OF OZONE IN THE HARTLEY BAND
CHASMAN, D
TANNOR, DJ
IMRE, DG
[J]. JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (11) : 6667 - 6675
[6] UNSYMMETRICAL B-1(2) (PI-PI-STAR) STATE OF OZONE
DEVAQUET, A
RYAN, J
[J]. CHEMICAL PHYSICS LETTERS, 1973, 22 (02) : 269 - 272
[7] THE PHOTODISSOCIATION OF O-3 - A CLASSICAL DYNAMIC APPROACH FOR THE INTERPRETATION OF THE RECURRENCES IN THE AUTOCORRELATION FUNCTION
FARANTOS, SC
TAYLOR, HS
[J]. JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (07) : 4887 - 4895
[8] WAVE PACKET DYNAMICS AND PHASE-SPACE STRUCTURE OF HCN MOLECULE
FARANTOS, SC
FOUNARGIOTAKIS, M
[J]. CHEMICAL PHYSICS, 1990, 142 (03) : 345 - 359
[9] SOLUTION OF THE SCHRODINGER-EQUATION BY A SPECTRAL METHOD
FEIT, MD
FLECK, JA
STEIGER, A
[J]. JOURNAL OF COMPUTATIONAL PHYSICS, 1982, 47 (03) : 412 - 433
[10] PERIODIC-ORBITS, BIFURCATIONS, AND QUANTUM-MECHANICAL EIGENFUNCTIONS AND SPECTRA
FOUNARGIOTAKIS, M
FARANTOS, SC
CONTOPOULOS, G
POLYMILIS, C
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (03) : 1389 - 1402

← 1 2 3 4 →