ISOLATION OF A SPIN-FRUSTRATED IMIDAZOLATE-BRIDGED TRINUCLEAR COPPER(II) COMPLEX POTENTIALLY RELEVANT TO THE MULTICOPPER OXIDASES

被引：85

作者：

CHAUDHURI, P

KARPENSTEIN, I

WINTER, M

BUTZLAFF, C

BILL, E

TRAUTWEIN, AX

FLORKE, U

HAUPT, HJ

机构：

[1] UNIV GESAMTHSCH PADERBORN,W-4790 PADERBORN,GERMANY

[2] MED UNIV LUBECK,INST PHYS,W-2400 LUBECK,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 04期

关键词：

D O I：

10.1039/c39920000321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Cu(MeCO2)2.H2O with 1,4,7-trimethyl-1,4,7-triazacyclononane (L) and imidazole (lmH) in methanol affords, in the presence of a small amount of triethylamine and NaClO4, the blue trinuclear complex [L3Cu3(lm)3](ClO4)3 which has been characterized by X-ray crystallography, EPR and magnetic susceptibility measurements to be a spin-frustrated triangular imidazolate-bridged copper(II) complex without any mu-3-X ligand.

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页码：321 / 322

页数：2

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